In general the west facing side(s) is the one needing most protection from late afternoon sun. Do you have a possibility of changing the house orientation to make it more aligned with E-W axis?
There are many ways to minimize heat.
Fewer windows on that site, insulated house walls, roof overhangs, shade trees, high fences, walk-in closets on the inside, awnings etc, etc.
Plus insulative qualities of the roof and ceiling.
There are also many other things to consider like local climate (night temperatures and strength/direction of prevalent winds).