You haven't mentioned if you've already planned or priced out the rest of your house project.
Just a word of advice...(Please disregard if money is no object).
It's only natural to desire the best available materials.
But the vast majority of us don't have a luxury of unlimited budgets.
The Roof is not the only component that determines overall quality of a structure.
Quality of the builder, walls, windows, ceilings (insulation), doors, thermal design/house orientation, shading, furniture and amenities...
All will have to compete for and be balanced out within your particular budget.
You've mentioned that you don't want to build a hot box.
The super-duper roof alone won't help you in achieving a well insulated dwelling.