As of April 2022, the priority service was still available for UK Visitor Visas.
At the end of the application, you'll be directed to select and pay for the service required and book an appointment for biometrics.
Two friends applied in April.
One for the 5-year Visitor Visa, and under the assumption applications were taking up to 10 weeks, paid for the priority service.
It was approved after 3 days.
The second submitted a standard application, standard fee, and it was approved after 10 days.
Both had previous Visa applications approved.