G/F is coming to on a Tourist Visa, my question is if we want to go to Spain or another European country can we get the Shenghen Visa in person at the Embassy ? Is the process very long ?

She must apply for the Schengen visa from the embassy of the country you wish to travel to in the country where she is resident.

Do a search on this forum on the words 'Schengen' and 'Spain' and you should get lots of info.